A New Strategy of Designing New Crystal Structures Based on Topological Structure: Syntheses and Crystal Structures of Five Coordination Polymers with (4,4) Topology
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https://figshare.com/articles/dataset/A_New_Strategy_of_Designing_New_Crystal_Structures_Based_on_Topological_Structure_Syntheses_and_Crystal_Structures_of_Five_Coordination_Polymers_with_4_4_Topology/2409424
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资源简介：
Five coordination polymers 1–5 with four types of (4,4) layers have
been synthesized through a
new strategy of designing their crystal structures based on (4,4)
topology. Compound [Co(adc)(bpp)(H2O)]n (1) presents a 2-D structure
with 2-fold homointerpenetration of layer A, while the
2-D compound {[Ni(adc)(bpp)2(H2O)]2·bpp}n (2) presents 2-fold heterointerpenetration of layer B and
layer C. Compound [Zn(adc)(bpp)·DMF]n (3) displays a typical 2-D
→ 3-D parallel interpenetrating structure of layer D. Compounds [Ni(Cladc)(bpp)(H2O)]n (4) and [Co(Cladc)(bpp)(H2O)]n (5) are isomorphous
and display similar structures to 1. (H2adc
= 4,4′-azodibenzoic acid, ClH2adc = 3,3′-dichloro-4,4′-azodibenzoic
acid, bpp = 1,3-di(4-pyridyl)propane, DMF = N,N-dimethylformamide). Luminescence properties
and thermal stabilities of 1–5 have
been explored.
创建时间：
2013-06-05
