Luminescent Heterometallic Branched Alkynyl Complexes of Rhenium(I)−Palladium(II): Potential Building Blocks for Heterometallic Metallodendrimers
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https://figshare.com/articles/dataset/Luminescent_Heterometallic_Branched_Alkynyl_Complexes_of_Rhenium_I_Palladium_II_Potential_Building_Blocks_for_Heterometallic_Metallodendrimers/3321643
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资源简介：
The photophysical and electrochemical behavior of a novel series of luminescent rhenium(I) complexes bearing a trialkynyl ligand, [1,3-(HC⋮C)2-5-{(N∧N)(CO)3ReC⋮C}C6H3]
(N∧N = tBu2bpy 1, Me2bpy 2, bpy 3), and their heterometallic branched complexes,
[1,3-{Cl(PEt3)2PdC⋮C}2-5-{(N∧N)(CO)3ReC⋮C}C6H3] (N∧N = Me2bpy 4, bpy 5), have been
studied; the X-ray crystal structures of 2 and 5 have been determined. Density functional
theory calculations have also been carried out in order to probe the bonding in these
compounds.
创建时间：
2004-10-11
