Synthesis and Structure of Dicationic, Bis(gold) π-Alkene Complexes Containing a 2,2′-Bis(phosphino)biphenyl Ligand
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Dicationic_Bis_gold_Alkene_Complexes_Containing_a_2_2_Bis_phosphino_biphenyl_Ligand/2557243
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The dicationic bis(gold)-biarylphosphine π-alkene complexes {(P–P)[Au(π-alkene)]2}2+2SbF6– [P–P = 2,2′-bis(di-tert-butylphosphino)biphenyl; alkene = isobutylene, 1-pentene] were isolated in >95% yield from reaction of alkene with a 1:2 mixture of (P–P)(AuCl)2 and AgSbF6 and were characterized by NMR spectroscopy and X-ray crystallography.
创建时间：
2016-02-22
