Asymmetric Total Synthesis of (−)-Clovan-2,9-dione Using Rh(I)-Catalyzed [3 + 2 + 1] Cycloaddition of 1‑Yne-vinylcyclopropane and CO
收藏Figshare2017-11-07 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Total_Synthesis_of_-Clovan-2_9-dione_Using_Rh_I_-Catalyzed_3_2_1_Cycloaddition_of_1_Yne-vinylcyclopropane_and_CO/5577439
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资源简介：
The asymmetric total synthesis of clovan-2,9-dione with a [6.3.1.01,5]dodecane skeleton has been achieved. The synthesis features a Rh(I)-catalyzed [3 + 2 + 1] cycloaddition of 1-yne-vinylcyclopropane (1-yne-VCP) with CO and an intramolecular aldol reaction to obtain the skeleton of the target molecule.
创建时间：
2017-11-07
