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Synthesis, Photophysics, Electrochemistry, Theoretical, and Transient Absorption Studies of Luminescent Copper(I) and Silver(I) Diynyl Complexes. X-ray Crystal Structures of [Cu<sub>3</sub>(μ-dppm)<sub>3</sub>(μ<sub>3</sub>-η<sup>1</sup>-C⋮CC⋮CPh)<sub>2</sub>]PF<sub>6</sub> and [Cu<sub>3</sub>(μ-dp

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A series of soluble trinuclear copper(I) and silver(I) complexes containing bicapped diynyl ligands, [M3(μ-dppm)3(μ3-η1-C⋮CC⋮CR)2]PF6 (M = Cu, R = Ph, C6H4CH3-p, C6H4OCH3-p, nC6H13, H; M = Ag, R = Ph, C6H4OCH3-p), has been synthesized and their electronic, photophysical, and electrochemical properties studied. The X-ray crystal structures of [Cu3(μ-dppm)3(μ3-η1-C⋮CC⋮CPh)2]PF6 and [Cu3(μ-dppm)3(μ3-η1-C⋮CC⋮CH)2]PF6 have been determined.

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2004-06-16
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