five

Chemoenzymatic Total Synthesis and Reassignment of the Absolute Configuration of Ribisin C

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Chemoenzymatic_Total_Synthesis_and_Reassignment_of_the_Absolute_Configuration_of_Ribisin_C/2336674
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The enantiomerically pure and enzymatically derived cis-1,2-dihydrocatechol 5 has been converted, by two related pathways, into compounds 3 and ent-3. As a result, it has been determined that the true structure of the natural product ribisin C is represented by ent-3.
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2016-02-18
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