Dimerization Control in the Self-Assembly Behavior of Copillar[5]arenes Bearing ω‑Hydroxyalkoxy Groups
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https://figshare.com/articles/dataset/Dimerization_Control_in_the_Self_Assembly_Behavior_of_Copillar_5_arenes_Bearing_Hydroxyalkoxy_Groups/2476546
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资源简介：
Two novel copillar[5]arenes bearing ω-hydroxyalkoxy
groups
are synthesized and their self-assembly properties are studied by 1H NMR spectroscopy, specific viscosity, and X-ray measurements.
The copillar[5]arene 2b bearing a 6-hydroxyhexyloxy group
exhibits a reversible self-assembly behavior, leading to the formation
of the self-inclusion monomer and hugging dimers. The reversible self-assembly
behavior can be controlled by tuning solvent, temperature, guest,
and H-bond interaction. However, the copillar[5]arene 2a bearing a short 4-hydroxybutyloxy group does not show such a self-assembly
behavior to the formation of the self-inclusion monomer and hugging
dimers.
创建时间：
2016-02-20
