Bench-Stable 5‑Stannyl Triazoles by a Copper(I)-Catalyzed Interrupted Click Reaction: Bridge to Trifluoromethyltriazoles and Trifluoromethylthiotriazoles
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https://figshare.com/articles/dataset/Bench-Stable_5_Stannyl_Triazoles_by_a_Copper_I_-Catalyzed_Interrupted_Click_Reaction_Bridge_to_Trifluoro_methyl_triazoles_and_Trifluoro_methyl_thiotriazoles/4829356
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资源简介：
Metalated triazoles are the key reactive
intermediate of the current
click reaction (CuAAC). Bench-stable 5-stannyl triazoles are obtained
by a copper-catalyzed interrupted click reaction of easily available
terminal alkynes. Subsequent palladium-catalyzed cross-coupling reactions,
electrophilic trifluoromethylthiolation and trifluoromethylation,
generate diverse 1,4,5-trisubstituted triazoles efficiently, which
the traditional click reaction is unable to do.
创建时间：
2017-04-07
