[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F···H···F– Bridges in a One-Dimensional Polymeric Chain
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https://figshare.com/articles/dataset/_Ni_HF_sub_2_sub_3_Clpy_sub_4_sub_BF_sub_4_sub_py_pyridine_Evidence_for_Spin_Exchange_Along_Strongly_Distorted_F_H_F_sup_sup_Bridges_in_a_One_Dimensional_Polymeric_Chain/2505082
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[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN4F2 octahedra that form chains with bridging HF2– ligands. In spite of significant distortion of the HF2– bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with JFHF = 4.86 K.
创建时间:
2016-02-20



