Regioselective Preferential Nucleophilic Addition of <i>N</i>-Heterocycles onto Haloarylalkynes over <i>N</i>-Arylation of Aryl Halides
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The study of preferential addition of heterocyclic amines onto halo-substituted arylalkynes over N-arylation under various catalytic conditions is described. The present work supports and confirms the mechanistic pathway of our recent work on the tandem synthesis of indolo- and pyrrolo-[2,1-a]isoquinolines via hydroamination followed by oxidative addition and not vice versa.
创建时间：
2012-02-17
