Trans Additions of Silanes to 1-Alkynes Catalyzed by Ruthenium Complexes: Role of in Situ Formed Polynuclear Aggregates
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https://figshare.com/articles/dataset/Trans_Additions_of_Silanes_to_1-Alkynes_Catalyzed_by_Ruthenium_Complexes_Role_of_in_Situ_Formed_Polynuclear_Aggregates/3773454
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资源简介：
(Z)-Alkenyl ligands are formed by insertion
of 1-alkynes into bridging hydrides. The unusual stereoselectivity of this elementary step may account for the
selectivity toward (Z)-alkenylsilanes frequently observed
in 1-alkyne hydrosilylations catalyzed by basic late-transition-metal complexes.
创建时间：
2016-08-26
