Skeleton Reassignment of Type C Polycyclic Polyprenylated Acylphloroglucinols
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https://figshare.com/articles/dataset/Skeleton_Reassignment_of_Type_C_Polycyclic_Polyprenylated_Acylphloroglucinols/4503125
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The previous assignment of the type C skeleton of polycyclic polyprenylated acylphloroglucinols (PPAPs) was controversial and proved to be incorrect in this study. The structures of the type C PPAPs (3–6) were revised to corresponding type A structures (3a–6a) via 13C NMR spectroscopic analysis and a quantum computational chemistry method. Therefore, only types A and B PPAPs are likely present in plants of the family Clusiaceae.
创建时间:
2016-12-29



