[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes

The first 3d–4f–5d heterotrimetallic complexes
using
[WV(bipy)­(CN)6]− as a metalloligand
were synthesized (bipy = 2,2′-bipyridine). The structural and
magnetic properties of three [CuIILnIIIWV] complexes (Ln = Gd, Ho, Tb) are discussed.

本研究所合成的首例以 [WV(bipy)(CN)6]− 作为金属配体的 3d–4f–5d 异金属三元配合物（其中 bipy 代表 2,2′-联吡啶）。文章深入探讨了三种 [CuIILnIIIWV] 配合物（Ln 分别为 Gd、Ho、Tb）的晶体结构与磁性特性。