Neo-N-confused Phlorins and Phlorinone: Rational Synthesis and Tunable Properties
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https://figshare.com/articles/dataset/Neo-N-confused_Phlorins_and_Phlorinone_Rational_Synthesis_and_Tunable_Properties/4579003
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资源简介：
By the acid-catalyzed [2 + 2] condensation,
an unprecedented neo-N-confused
phlorin (neo-NCphlorin 1) was successfully synthesized.
By treating 1 with N-chlorosuccinimide, the corresponding
chloro-substituted neo-NCphlorin (1-Cl) was obtained. The oxidization
of 1 with FeCl3 afforded the neo-N-confused phlorinone
(neo-NCphlorinone 2), which bears a relatively coplanar
conformation, different from the highly distorted ones observed for 1 and 1-Cl. Notably, 2 shows striking
long-wavelength absorption beyond 1300 nm upon addition of TBAF.
创建时间：
2017-01-23
