Unexpected Reactivities of Cu<sub>2</sub>(diphosphine)<sub>2</sub> Complexes in Alcohol: Isolation, X-ray Crystal Structure, and Photoluminescent Properties of a Remarkably Stable [Cu<sub>3</sub>(diphosphine)<sub>3</sub>(<i>μ</i><sub>3</sub>-H)]<sup>2+</sup> Hydride Complex
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https://figshare.com/articles/dataset/Unexpected_Reactivities_of_Cu_sub_2_sub_diphosphine_sub_2_sub_Complexes_in_Alcohol_Isolation_X_ray_Crystal_Structure_and_Photoluminescent_Properties_of_a_Remarkably_Stable_Cu_sub_3_sub_diphosphine_sub_3_sub_i_i_sub_3_sub_H_sup_2_sup_Hydride_Complex/3292348数据链接链接失效反馈
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资源简介：
Treatment of [Cu2(dcpm)2]Y2 (dcpm = bis(dicyclohexylphosphino)methane, Y = ClO4-, BF4-, PF6-, CF3SO3-) with refluxing MeOH in the presence of KOH afforded hydride complexes [Cu3(dcpm)3(μ3-H)]Y2 (1) in about 85% yield. Refluxing [Cu2(dcpm)2](PF6)2 with MeOH in the presence of NH3·H2O and air gave a carboxylate complex [Cu2(dcpm)2(O2CCH2OH)]PF6 (2) in 40% yield. All of the complexes 1 and 2 have been characterized by X-ray crystallography. The Cu3 cores in 1 are almost perfectly shielded by the dcpm ligands. Intense photoluminescence was observed for 1 both in the solid state and in solution.
创建时间：
2016-05-06
