Stoichiometric Metal-Free Reduction of CO in Syn-Gas
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https://figshare.com/articles/dataset/Stoichiometric_Metal_Free_Reduction_of_CO_in_Syn_Gas/2428948
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资源简介：
Reaction
of a 2:1 mixture of B(C6F5)3 and tBu3P with syn-gas results
in the stoichiometric reduction of CO to give a formyl derivative
which reacts further via an epoxy-borate intermediate to capture CO,
affording a heterocylic alkoxyborate. Heating the reaction prompts
reaction with H2 to give a borane-oxy-borate derivative,
the product of C–O bond cleavage.
创建时间：
2016-02-19
