Charge Ordering and Carrier Generation by Air Oxidation of a Nickel Complex with Selenium-Containing Extended-Tetrathiafulvalenedithiolate Ligands
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https://figshare.com/articles/dataset/Charge_Ordering_and_Carrier_Generation_by_Air_Oxidation_of_a_Nickel_Complex_with_Selenium_Containing_Extended_Tetrathiafulvalenedithiolate_Ligands/2544547
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资源简介：
The structures and electrical properties of (nBu4N)[Ni(dmstfdt)2] (1),
(nBu4N)2[Ni(dmstfdt)2] (2), and (nBu4N)3[Ni(dmstfdt)2]2 (3), where dmstfdt = extended-tetrathiafulvalenedithiolate
ligand, were examined. The fresh crystal of 1 was found
to be a Mott insulator, but the crystal gradually became highly conducting
because of air oxidation. Compound 3 exhibited a semiconducting
charge-ordering state.
创建时间：
2012-03-05
