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Layered Heterometallic Iodoplumbate Containing a Novel Pb<sub>3</sub>Cu<sub>6</sub>I<sub>16</sub> Net: Structure and Optical Properties

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NIAID Data Ecosystem2026-03-06 收录
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A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)3]2[Pb3Cu6I16]·C2H5OH, contains a novel Pb3Cu6I16 net made up of linked Pb3I11 and Cu6I11 clusters. The clusters form a BN-type layer, where the Pb3I11 and Cu6I11 clusters take the place of B and N. The layers, which are separated by [Co(phen)3]2+ cations, contain cavities in which ethanol molecules are located.

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2006-12-25
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