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A Neutral Pentacoordinate Silicon(IV) Complex with a Monodentate Nitrato Ligand: Synthesis and Structural Characterization

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https://figshare.com/articles/dataset/A_Neutral_Pentacoordinate_Silicon_IV_Complex_with_a_Monodentate_Nitrato_Ligand_Synthesis_and_Structural_Characterization/2897959
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资源简介:
The neutral pentacoordinate nitratosilicon(IV) complex 7 was synthesized by treatment of the corresponding chlorosilicon(IV) complex 8 with Me3SiONO2 (Cl/ONO2 exchange). Compound 7 is the first higher-coordinate silicon compound with an Si−ONO2 group that could be structurally characterized both in solution (1H, 13C, and 29Si NMR) and in the solid state (VACP/MAS 13C and 29Si NMR, crystal structure analysis of 7·CH2Cl2).
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2016-02-27
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