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Syntheses and Structure of the Solvent-Separated Calcium Cuprate [(thf)3Ca(μ-Ph)3Ca(thf)3]+[Ph−Cu−Ph]-

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Figshare2007-07-02 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Syntheses_and_Structure_of_the_Solvent-Separated_Calcium_Cuprate_thf_sub_3_sub_Ca_-Ph_sub_3_sub_Ca_thf_sub_3_sub_sup_sup_Ph_Cu_Ph_sup_-_sup_/12077364
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The transmetalation of phenylcopper yields the solvent-separated cuprate [(thf)3Ca(μ-Ph)3Ca(thf)3]+[Ph−Cu−Ph]-. This derivative extends the known classes of organic calcium compounds by an organometallic complex cation, in addition to the already well-known neutral diarylcalcium and trialkylcalciate anions.
创建时间:
2007-07-02
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