Directed Selenium–Iodine Halogen Bonding and Se···H–C Contacts in Solid Iododiisopropylphosphane Selenide
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https://figshare.com/articles/dataset/Directed_Selenium_Iodine_Halogen_Bonding_and_Se_H_C_Contacts_in_Solid_Iododiisopropylphosphane_Selenide/2566222
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资源简介：
Solid iododiisopropylphosphane selenide crystallizes
in the space
group P21/n with one
molecule iPr2P(I)Se in the asymmetric
unit. Halogen bonds of the type Se···I–P (Se···I,
3.612 Å; Se···I–P, 171°) connect the
molecules to form polymeric chains (-Se···I–P-)x. These are further connected by Se···H
contacts (2.98 Å) involving the tertiary H atom from one isopropyl
group. The extended structure thus formed is a layer parallel to 101̅,
and a substructure thereof consists of 10-membered (···Se···I–P–C–H···)2 rings.
创建时间：
2016-02-22
