Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes
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https://figshare.com/articles/dataset/Nitrene_Metathesis_and_Catalytic_Nitrene_Transfer_Promoted_by_Niobium_Bis_imido_Complexes/2096428
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资源简介：
We
report a metathesis reaction in which a nitrene fragment from
an isocyanide ligand is exchanged with a nitrene fragment of an imido
ligand in a series of niobium bis(imido) complexes. One of these bis(imido)
complexes also promotes nitrene transfer to catalytically generate
asymmetric dialkylcarbodiimides from azides and isocyanides in a process
involving the Nb(V)/Nb(III) redox couple.
创建时间：
2016-02-12
