Self-Assembly of a Nonanuclear Nickel(II) Complex and Its Magnetic Properties
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https://figshare.com/articles/dataset/Self_Assembly_of_a_Nonanuclear_Nickel_II_Complex_and_Its_Magnetic_Properties/3257494
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资源简介：
A nonanuclear nickel(II) complex [Ni9(PyA)10(μ3-OH)2(μ2-OH)2(μ2-OH2)2(H2O)6](ClO4)4·12H2O, containing pyridine-2-aldoximato monoanion, PyA, has been structurally and magnetochemically characterized. The nickel(II) ions, linked together via several bi- or
trifurcated oximato, hydroxo, and water bridges, are antiferromagnetically coupled with the coupling constants J1 = −26.5 cm-1
and J2 = −7.0 cm-1, resulting in a ground state of St = 1.
创建时间：
2016-05-05
