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Isonitrile Iron(II) Complexes with Chiral N2P2 Macrocycles in the Enantioselective Transfer Hydrogenation of Ketones

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Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Isonitrile_Iron_II_Complexes_with_Chiral_N_sub_2_sub_P_sub_2_sub_Macrocycles_in_the_Enantioselective_Transfer_Hydrogenation_of_Ketones/2223970
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Bis­(isonitrile) iron­(II) complexes bearing a C2-symmetric N2P2 macrocyclic ligand, which are easily prepared from the corresponding bis­(acetonitrile) analogue, catalyze the asymmetric transfer hydrogenation (ATH) of a broad scope of ketones in excellent yields (up to 98%) and with high enantioselectivity (up to 91% ee).
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2016-02-16
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