Metal-Free Iodine(III)-Promoted Direct Intermolecular C–H Amination Reactions of Acetylenes
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https://figshare.com/articles/dataset/Metal_Free_Iodine_III_Promoted_Direct_Intermolecular_C_H_Amination_Reactions_of_Acetylenes/2485594
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资源简介：
A direct metal-free amination of arylalkynes has been
developed,
which proceeds by reaction of the terminal alkyne with the hypervalent
iodine reagent PhI(OAc)NTs2 within a single-step operation.
This unprecedented intermolecular C–H to C–N bond conversion
provides rapid access to the important class of ynamides. In addition
to the title reaction, the related transformation between alkylated
alkynes and the iodine(III) reagent is also discussed.
创建时间：
2016-02-20
