Cupric Decamolybdodivanadophosphate. A Coordination Polymer Heterogeneous Catalyst for Rapid, High Conversion, High Selectivity Sulfoxidation Using the Ambient Environment
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https://figshare.com/articles/dataset/Cupric_Decamolybdodivanadophosphate_A_Coordination_Polymer_Heterogeneous_Catalyst_for_Rapid_High_Conversion_High_Selectivity_Sulfoxidation_Using_the_Ambient_Environment/3613314
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资源简介：
A new type of coordination network polymer involving the redox-active polyanion, PV2Mo10O405-, and bridging −CuII(OH2)4− units,
{[(CuII(OH2)4)3(OH)]PV2Mo10O40}n (1), has been characterized by
X-ray crystallography and several other methods. It is the first
efficient heterogeneous (insoluble) catalyst for selective and rapid
sulfoxidation using only the ambient environment (air at room
temperature). Catalytic activity is enhanced by soluble nitrate in
nontoxic perfluoropolyether (PFPE) media.
创建时间：
2016-08-17
