Hydrothermal synthesis, structure and properties of a new 3D two-fold Co-based coordination framework
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A new 3D coordination polymer, [Co<sub>2</sub>(MIP)<sub>2</sub>(BMIP)]<i><sub>n</sub></i> (<b>1</b>), [H<sub>2</sub>MIP = 5-methyl-isophthalic acid, BMIP = 1,5-bis-(2-methyl-imidazol)pentane] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that <b>1</b> has a two-fold interpenetrated 3D network with a <b>pcu</b> topology. In addition, the luminescent, electrochemical properties and degradation of MB and MO of the complex were studied. The photocatalytic mechanism was proposed and confirmed by trapping experiments of radical species.
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Taylor & Francis创建时间：
2020-12-02
