Isocyanide-Promoted Ylidene Transfer to Phosphorus: Rearrangement in the First-Generation Grubbs Complex
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https://figshare.com/articles/dataset/Isocyanide_Promoted_Ylidene_Transfer_to_Phosphorus_Rearrangement_in_the_First_Generation_Grubbs_Complex/2922277
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资源简介：
Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexylphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; a probable mechanism for the ligand-promoted transformation is also discussed.
创建时间：
2016-02-27
