Formal Synthesis of (±)-Roseophilin
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https://figshare.com/articles/dataset/Formal_Synthesis_of_Roseophilin/2889019
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资源简介:
A formal synthesis of (±)-roseophilin is described. Scandium(III)-catalyzed Nazarov cyclization of 2,5-disubstituted N-tosylpyrrole 19 gives a 5,5′-fused ketopyrrole, and ansa-bridge formation via π-allyl palladium macrocyclization gives 21.
创建时间:
2009-01-01



