Tris(oxazolinyl)boratomagnesium-Catalyzed Cross-Dehydrocoupling of Organosilanes with Amines, Hydrazine, and Ammonia
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We report magnesium-catalyzed cross-dehydrocoupling of Si–H and N–H bonds to give Si–N bonds and H2. A number of silazanes are accessible using this method, as well as silylamines from NH3 and silylhydrazines from N2H4. Kinetic studies of the overall catalytic cycle and a stoichiometric Si–N bond-forming reaction suggest nucleophilic attack by a magnesium amide as the turnover-limiting step.
创建时间：
2016-02-22
