Solid-to-Solid Oxidation of a Vanadium(IV) to a Vanadium(V) Compound: Chemisty of a Sulfur-Containing Siderophore
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https://figshare.com/articles/dataset/Solid_to_Solid_Oxidation_of_a_Vanadium_IV_to_a_Vanadium_V_Compound_Chemisty_of_a_Sulfur_Containing_Siderophore/2491633
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资源简介：
Visible light facilitates a solid-to-solid photochemical
aerobic
oxidation of a hunter-green microcrystalline oxidovanadium(IV) compound
(1) to form a black powder of cis-dioxidovanadium(V)
(2) at ambient temperature. The siderophore ligand pyridine-2,6-bis(thiocarboxylic
acid), H2L, is secreted by a microorganism from the Pseudomonas genus. This irreversible transformation of a
metal monooxo to a metal dioxo complex in the solid state in the
absence of solvent is unprecedented. It serves as a proof-of-concept
reaction for green chemistry occurring in solid matrixes.
创建时间：
2012-09-03
