Synthesis of Octatrimethylsilyl-[8]cycloparaphenylene for Multifunctionalized Cycloparaphenylene
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https://figshare.com/articles/dataset/Synthesis_of_Octatrimethylsilyl-_8_cycloparaphenylene_for_Multifunctionalized_Cycloparaphenylene/29175258
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资源简介:
Octatrimethylsilyl-[8]cycloparaphenylene ([8]CPP-8TMS)
was synthesized
using the copper(I)-mediated homocoupling reaction of the highly
functionalized biphenyl precursor and subsequent platinum-mediated
macrocyclization. [8]CPP-8TMS was well characterized by spectroscopic
techniques, including NMR, mass, UV–vis absorption, and fluorescence
spectroscopy and cyclic voltammetry. Single-crystal X-ray diffraction
analysis indicates that [8]CPP-8TMS possesses a highly symmetric structure
and adopts an intermolecular tubular packing. [8]CPP-8TMS can serve
as a versatile platform for the efficient construction of unprecedented
functional nanocarbon structures.
创建时间:
2025-05-28



