Carbon–Oxygen Bond Activation in Esters by Platinum(0): Cleavage of the Less Reactive Bond
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https://figshare.com/articles/dataset/Carbon_Oxygen_Bond_Activation_in_Esters_by_Platinum_0_Cleavage_of_the_Less_Reactive_Bond/2502952
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Reaction of Pt(dippe)(NBE)2 (NBE = norbornene) with a variety of esters leads to a product in which the less reactive C–O bond is cleaved to give Pt(dippe)(O2CR)(R′). A further disproportionation reaction occurs to eliminate R′2 and produce Pt(dippe)(O2CR)2. Details of the mechanisms of these reactions are explored.
创建时间：
2016-02-20
