Reaction of V(C6H6)2 with the Borane Adducts of Malononitrile [(C6F5)3B·NCCH2CN·B(C6F5)3] and Water [H2O·B(C6F5)3]
收藏Figshare2007-07-02 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Reaction_of_V_C_sub_6_sub_H_sub_6_sub_sub_2_sub_with_the_Borane_Adducts_of_Malononitrile_C_sub_6_sub_F_sub_5_sub_sub_3_sub_B_NCCH_sub_2_sub_CN_B_C_sub_6_sub_F_sub_5_sub_sub_3_sub_and_Water_H_sub_2_sub_O_B_C_sub_6_sub_F_sub_5_sub_sub_3_sub_/12075438
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资源简介：
Reaction of malononitrile, NCCH2CN, with V(C6H6)2 in toluene in the presence of 2 equiv of B(C6F5)3 afforded the vanadium(I) complex [V(C6H5Me)2][(F5C6)3B·NCCHCN·B-(C6F5)3], in which deprotonation of the malononitrile ligand and arene exchange at the vanadium center have occurred. In the absence of malononitrile, a redox reaction was observed between V(C6H6)2 and the water adduct H2O·B(C6F5)3, which gave the vanadium(I) complex [V(C6H6)2][(F5C6)3BOB(C6F5)2].
创建时间：
2007-07-02
