Efficient and Stereoselective Access to the Polyol Fragment C9−C16 of Ansamycin Antibiotics
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https://figshare.com/articles/dataset/Efficient_and_Stereoselective_Access_to_the_Polyol_Fragment_C9_C16_of_Ansamycin_Antibiotics/2834113
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资源简介：
Efficient synthesis of the fragment C9−C16 bearing the anti,syn stereotriad of ansamycin antibiotics is described. Key steps for controlling the configuration of the three stereogenic centers involve a stereoselective Reformatsky-type reaction followed by a diastereoselective reduction of a β-ketosulfoxide.
创建时间：
2016-02-26
