Acid-Mediated Ring-Expansion Reaction of N‑Aryl-2-vinylazetidines: Synthesis and Unanticipated Reactivity of Tetrahydrobenzazocines
收藏Figshare2016-02-17 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Acid_Mediated_Ring_Expansion_Reaction_of_i_N_i_Aryl_2_vinylazetidines_Synthesis_and_Unanticipated_Reactivity_of_Tetrahydrobenzazocines/2291014
下载链接
链接失效反馈官方服务：
资源简介：
The aza-Clasen rearrangement of N-aryl-2-vinylazetidines has been explored. N-Aryl-2-vinylazetidines were transformed to corresponding tetrahydrobenzazocines in good yields. Unexpectedly, the tetrahydrobenzazocine was unstable and readily isomerized to vinyltetrahydroquinoline in the presence of acid. The mechanism of this ring contraction was studied in detail.
创建时间：
2016-02-17
