Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides
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https://figshare.com/articles/dataset/Synthesis_of_Copper_I_Thiolate_Complexes_in_the_Thioetherification_of_Aryl_Halides/2466523
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资源简介：
The copper(I) thiophenolato complexes 1–3 containing 1,10-phenanthroline (phen) and 2,9-dimethyl-1,10-phenanthroline
(Me2phen) were isolated in excellent yields from reactions
of [CuOtBu]4 with the dative ligands and
subsequent addition of 1 equiv of arenethiol. These complexes were
characterized spectroscopically and crystallographically. X-ray structural
analysis of a single crystal of [(phen)Cu(μ-SC6H5)]2 (1) revealed that this complex
adopts a neutral dimeric form with a weak Cu–Cu bonding interaction.
These complexes were found to react with iodoarenes to form aryl sulfide
products. The intermediacy of such complexes in copper-catalyzed thioetherification
of aryl halides was demonstrated by the reactivity with p-tolyl iodide and o-tolyl iodide to form two aryl
thioethers with selectivities similar to those of catalytic reactions
conducted with the same two iodoarenes.
创建时间：
2012-11-26
