Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches
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https://figshare.com/articles/dataset/Tetra-_and_Octapyrroles_Synthesized_from_Confusion_and_Fusion_Approaches/3848193
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资源简介：
By oxidation of an alternately N-confused
bilane in CH2Cl2, a C–N fused tetrapyrrin
was synthesized that
bears a 5.5.5-tricyclic ring generated from an intramolecular C–N
linkage. When CH3CN was used as the reaction medium, a
multiply C–N-fused octapyrrolic dimer was also obtained that
contained two 5.5.5.7.5-pentacyclic moieties and a bipyrrole unit
generated from the intramolecular C–N linkage and intermolecular
C–C linkage, respectively. This could be coordinated with Ni(acac)2 to afford a mixed-ligand complex.
创建时间：
2016-10-03
