A New Molybdenum-Oxide-Based Organic−Inorganic Hybrid Compound Templated by 5-(2-Pyridyl)tetrazole with New Topology and Canted Antiferromagnetism

A new three-dimensional Mo/O/MnII/tetrazole compound [Mn(ptz)Mo2O7] (1) (ptz = 5-(2-pyridyl)tetrazole) was synthesized by a hydrothermal method. It represents the first example of a molybdenum-oxide-based organic−inorganic hybrid compound templated by the ligand which connects both molybdenum and secondary metal simultaneously. The magnetic investigations reveal that the complex exhibits interesting spin-canting antiferromagnetism, and the structure studies show that compound 1 is a (4,6)-connected framework with novel (33,42,5)(34,42,62,74,82,9)(34,44,52,64,7)2 topology that has never been reported to date.