Room-Temperature Bistability in Spin Crossover-Loaded Metal–Organic Frameworks
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https://figshare.com/articles/dataset/Room-Temperature_Bistability_in_Spin_Crossover-Loaded_Metal_Organic_Frameworks/21803265
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资源简介：
In this article, we present an unprecedented strategy
to prepare bistable
porous nanocrystals based on the anchoring of switchable molecules
in the pores of a host matrix through strong host–guest interactions.
More precisely, we have inserted a prototypical Fe(III) spin-crossover
complex in MOF-808, a chemically robust large-pore Zr-based MOF. The
loaded nanocrystals present a hysteretic thermal spin transition close
to room temperature that is independent of the complex loading and
the MOF particle size while remaining highly porous, which opens up
opportunities for their use as chemical sensors.
创建时间：
2023-01-02
