Efficient Cage-Opening Cascade Process for the Preparation of Water-Encapsulated [60]Fullerene Derivatives
收藏NIAID Data Ecosystem2026-03-06 收录
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Cage-opened fullerenes with 18-membered-ring orifices have been prepared starting from fullerene-mixed peroxides. The key transformation involves a cascade sequence including a deketalization, a SN2′ epoxide opening reaction, and a formal 3,3-σ rearrangement. The 18-membered-ring orifice is big enough for water encapsulation under mild conditions. Single crystal X-ray structures were obtained for both the empty and water-encapsulated fullerene derivatives.
创建时间：
2016-02-26
