A Monolithiated and Its Related 1,3-Dilithiated Benzylsilane: Syntheses and Crystal Structures
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/A_Monolithiated_and_Its_Related_1_3-Dilithiated_Benzylsilane_Syntheses_and_Crystal_Structures/3766752
下载链接
链接失效反馈官方服务：
资源简介：
The monolithiated (aminomethyl)benzylsilane Me2Si[CHLi(C6H5)](CH2NC5H10) (3) and the corresponding 1,3-dilithiated compound Me2Si[CHLi(o-C6H4Li)](CH2NC5H10) (4) (CH2NC5H10 = piperidinomethyl), metalated at the benzyl position and at the ortho
position of the phenyl ring, were obtained by successive
deprotonation of Me2Si[CH2(C6H5)](CH2NC5H10) (1).
Monolithiated 3, an internally coordinated cyclic tetramer, and 1,3-dilithiated 4, an internally coordinated
cyclic hexamer, were structurally characterized by single-crystal X-ray diffraction methods.
创建时间：
2016-08-26
