Total Synthesis of Taiwaniadducts B, C, and D
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https://figshare.com/articles/dataset/Total_Synthesis_of_Taiwaniadducts_B_C_and_D/2283544
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资源简介：
The first total syntheses
of taiwaniadducts B, C, and D have been
accomplished. Two diterpenoid segments were prepared with high enantiopurity,
both through Ir-catalyzed asymmetric polyene cyclization. A sterically
demanding intermolecular Diels–Alder reaction promoted by Er(fod)3 assembled the scaffold of taiwaniadducts B and C. A carbonyl-ene
cyclization forged the cage motif of taiwaniadduct D at a late stage,
providing over 200 mg of this compound.
创建时间：
2014-06-11
