Reduction of a Kinetically Stabilized Silabenzene Leading to the Formation of the Corresponding Anion Radical Species
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https://figshare.com/articles/dataset/Reduction_of_a_Kinetically_Stabilized_Silabenzene_Leading_to_the_Formation_of_the_Corresponding_Anion_Radical_Species/2958439
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资源简介:
An electrochemical study of kinetically stabilized silabenzene, 1-{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}silabenzene (1), revealed that its reduction potential is –2.96 V (vs Cp2Fe/Cp2Fe+), which is lower than that of naphthalene. The anion radical species of 1 was generated by one-electron reduction using lithium naphthalenide and characterized by ESR spectroscopy.
创建时间:
2016-02-27



