Strategy for Selective Csp2–F and Csp2–Csp2 Formations from Organoplatinum Complexes
收藏Figshare2026-04-28 收录
下载链接：
https://figshare.com/articles/dataset/Strategy_for_Selective_C_sub_sp2_sub_F_and_C_sub_sp2_sub_C_sub_sp2_sub_Formations_from_Organoplatinum_Complexes/13521463
下载链接
链接失效反馈官方服务：
资源简介：
By changing the parameters of fluorination reaction of bisaryl-platinum(II) complexes, each possible competitive pathway of Ar–Ar and Ar–F formation can be selectively controlled. It was discovered that steric hindrance, type of fluorinating reagent, and temperature of reaction are determinants for Ar–F vs Ar–Ar bond formation pathway from bisaryl-fluoro-platinum(IV) complexes. The combination of bulky ligands such as mesityl with Selectfluor at RT leads to Ar–F bond formation in the presence of possible Ar–Ar formation.
