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Highly Diastereoselective Oxidative Addition of Methyl Iodide to a Chiral Square-Planar Complex

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Highly_Diastereoselective_Oxidative_Addition_of_Methyl_Iodide_to_a_Chiral_Square_Planar_Complex/3063751
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资源简介:
Oxidative addition of methyl iodide to the chiral square-planar complex IrI(CO)(duphos) shows a high level of diastereoselectivity. The basis for the diastereoselectivity of the reaction is best explained based on the crystal structure of IrI(CO)(duphos) in which methyl iodide approach across the two faces is differentiated by the chiral ligand.
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2016-02-29
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