Regioselective Hydromethoxycarbonylation of Terminal Alkynes Catalyzed by Palladium(II)–Tetraphos Complexes
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https://figshare.com/articles/dataset/Regioselective_Hydromethoxycarbonylation_of_Terminal_Alkynes_Catalyzed_by_Palladium_II_Tetraphos_Complexes/2506957
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An in situ generated dinuclear palladium hydride complex bearing cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)cyclobutane catalyzed the hydromethoxycarbonylation of terminal alkynes, giving the corresponding branched α,β-unsaturated ester (A) with high regioselectivity.
创建时间:
2016-02-20



