Asymmetric Total Synthesis of (−)-Aspidophylline A
收藏NIAID Data Ecosystem2026-03-10 收录
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资源简介：
An asymmetric total synthesis of (−)-aspidophylline A has been accomplished. The key transformations include an asymmetric hydride transfer hydrogenation of an α,β-acetylenic ketone and a cationic gold(I)-catalyzed 6-exo-dig cyclization involving an alkynylindole/aminal formation cascade, which enables stereoselective establishment of the requisite quaternary carbon center.
创建时间：
2017-03-23
