Rhodium Complexes of a New Structurally Adaptive PNN-Pincer Type Ligand
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https://figshare.com/articles/dataset/Rhodium_Complexes_of_a_New_Structurally_Adaptive_PNN_Pincer_Type_Ligand/2411803
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资源简介：
A new PNN-pincer type ligand with
pyrazolyl and diphenylphosphine
flanking donors on a diarylamido anchor has been prepared. Its bis(tert-butyl isocyanide)rhodium(I) complex exhibits hemilabile
behavior in solution, and its solid-state structure verified the elusive
κ2P,N coordination
mode for this type of
ligand. Reactions between (PNN)Rh(CNtBu)2 and
iodomethane afford both fac- and cis,mer-[(PNN)Rh(CNtBu)2(Me)](I), which further showcases the structural versatility
of the ligand.
创建时间：
2016-02-19
