Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile
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https://figshare.com/articles/dataset/Reactivity_of_Seven_Membered_Azazirconacycloallenes_and_Four_Membered_Zirconacycles_toward_Diphenylacetonitrile/2461897
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资源简介：
The reaction of the seven-membered azazirconacycloallene 2 with Ph2CHCN was carried out to yield a zirconocene
complex with three fused rings and a keteniminate ligand. Further
reactivity toward propargyl bromide or propionyl chloride shows that
the keteniminate ligand can be replaced by halogen atoms (Br or Cl).
In addition, the reaction of the strained four-membered zirconacycle 1 with Ph2CHCN gives zirconocenes possessing vinyl-imine
and keteniminate species.
创建时间：
2016-02-20
